Probing P25 TiO<sub>2</sub> photocatalysis using photoinduced absorption spectroscopy (PIAS)
نویسندگان
چکیده
Photoinduced absorption spectroscopy (PIAS) is used to probe the kinetics of oxidation 4-chlorophenol, 4CP, by P25 TiO2 with anodic bias or using a sacrificial electron acceptor and establishes first order for reaction h+ 4CP.
منابع مشابه
Photoinduced absorption spectroscopy of dye-sensitized nanostructured TiO2
Photoinduced absorption (PIA) spectroscopy was used to investigate dye-sensitized electrodes and solar cells under illumination conditions comparable to sunlight. In the absence of redox electrolyte, cis-RuðdcbpyÞ2ðNCSÞ2-sensitized nanostructured TiO2 films show a long-lived photoinduced charge-separation (oxidized dye molecules/injected electrons in TiO2), with a lifetime of about 10 3 s under...
متن کاملProbing Cu(I) in homogeneous catalysis using high-energy-resolution fluorescence-detected X-ray absorption spectroscopy.
Metal-to-ligand charge transfer excitations in Cu(I) X-ray absorption spectra are introduced as spectroscopic handles for the characterization of species in homogeneous catalytic reaction mixtures. Analysis is supported by correlation of a spectral library to calculations and to complementary spectroscopic parameters.
متن کاملProbing the Mechanism of High Capacitance in 2D Titanium Carbide Using In Situ XRay Absorption Spectroscopy
(comparable only with hydrated RuO 2 ) was measured for Ti 3 C 2 T x in aqueous electrolytes. [ 11,14 ] Our previous studies revealed that spontaneous intercalation of some cations takes place when MXene samples are exposed to aqueous electrolytes. [ 6 ] In situ X-ray diffraction showed that variations of the distance between the Ti 3 C 2 T x layers (which is proportional to the c lattice param...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Chemical Communications
سال: 2021
ISSN: ['1359-7345', '1364-548X']
DOI: https://doi.org/10.1039/d0cc07794a